So is there a concern for the "white film" with PBW? I gave up on it due to this. Luckily I was able to get it out with lots of iso and salt washes and very hot water, and vinegar.
I didnt get any white film both times I've used it, but I rinsed with cold water thoroughly after the wash.
The hard water theory is sound. In Montreal you'll get 150ppm but in the GTA you could get as much as 300ppm in some places. It depends on what kind of filtration and treatment system the city uses.
If you want to be very anal about cleaning I would invest in a RO filter and make my own 0ppm water, then boil that and use it for the cleaning with PBW. Boiling water on an induction boiler literally takes seconds, and with a RO filter you could keep a few 1 gallon jugs around for a quick and easy clean.
It's worth looking into when you're taking about expensive glass like a Mobius piece.