EitherOr said:
Hello CD, I really like the look of your glass stems. Very creative! I cant wait to see what other products you can come up with.
In regards to the compound you use, would it be possible for you to share the MSDS (Material Safety Data Sheet) or it's equivalent for this product? It's(the compounds) contents or make up perhaps? Preferably with information from a verifiable 3rd party source other than the compounds manufacturer.
I ask this as you state that the manufacturer has told you that no toxins can be 'released' below 600f. Does that mean there are toxins and they can be released above 600f? If so, it should probably be stated as so, even if the temps are too low for anything to be released.
I am certainly not trying to put you 'on the spot', but as others have stated this forum's purpose is for information sharing, as to allow us all to make the most informed decisions about the products we use. For this concept to truly work we must apply it to every product discussed or offered on this site.
Hardener -
=================================================================================
SECTION II - HAZARDOUS INGREDIENTS
=====================================================================
INGREDIENTS WGT% CAS # TLV/PEL
Calcium Carbonate 30-40% 1317-65-3 ACGIH TWA 10 mg/m3
OSHA PEL 15 mppcf
Barium Sulfate 20-30% 7727-43-7 ACGIH TWA 10 mg/m3
OSHA PEL 2 mppcf
Magnesium Silicate 5-10% 14807-96-6 ACGIH TWA 2 mg/m3
OSHA PEL 20 mppcf
Titanium Dioxide 1-5% 13463-67-7 ACGIH TWA 10 mg/m3
OSHA PEL 20 mg/m3
Zinc Sulfide 0-5% 1314-98-3 ACGIH TLV 10 mg/m3
Furfuryl Alcohol 1-5% 98-00-0 ACGIH TWA 10 ppm
Polyamide Resin 15-25% 68410-23-1 N/E
Aminophenols 1-5 % Mixture N/E
=================================================================================
SECTION III - PHYSICAL DATA
=====================================================================
APPEARANCE: White Paste
SPECIFIC GRAVITY: 1.78
VAPOR PRESSURE (mmHG): N/Av
BOILING POINT: N/Av
VAPOR DENSITY: Heavier than air
EVAPORATION RATE (Ethyl Ether = 1): Slower than Ethyl Ether
VOLATILES BY WEIGHT: Nil
SOLUBILITY IN WATER: Not Soluble
VOC: Grams/Liter = 72
Lbs/Gallon = 0.6
PAGE 2 of 4 EPOXY STEEL HARDENER
==============================================================================
SECTION IV - FIRE AND EXPLOSION DATA
=================================================================================
FLASH POINT: .>200F/93C Seta Flash Closed cup
LOWER FLAMMABLE LIMIT %: N/E
UPPER FLAMMABLE LIMIT %: N/E
FIRE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers with water
spray. Firefighter should wear OSHA/NIOSH approved self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARD: Closed containers exposed to high temperatures, such as fire
conditions may rupture.
=================================================================================
SECTION V - HEALTH HAZARD/TOXICOLOGICAL PROPERTIES
=================================================================================
OVEREXPOSURE EFFECTS:
ACUTE EFFECTS:
EYES: Contact with eyes can cause severe irritation, redness, tearing, blurred vision, and/or swelling.
May cause eye damage.
SKIN: Contact with skin can cause irritation, (minor itching, burning and/or redness), Dermatitis,
defatting may be readily absorbed through the skin.
INHALATION: Inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness,
fatigue, nausea, headache, possible unconsciousness and/or asphyxiation. Aspiration of material into
lungs may result in chemical pneumonitis which can be fatal.
INGESTION: Ingestion can cause gastrointestinal irritation, nausea, vomiting, diarrhea.
CHRONIC EFFECTS:
Overexposure to this material has apparently been known to cause the following effects in lab animals:
Eye damage, skin damage.
CARCINOGEN: YES _____ NO __X__
TERATOGEN: YES _____ NO __X__
MUTAGEN: YES _____ NO __X__
PRIMARY ROUTES OF EXPOSURE: Skin, inhalation
FIRST AID:
INHALATION: If inhaled, remove victim from exposure to a well-ventilated area. Make them
comfortably warm, but not hot. Use oxygen or artificial respiration as required. Consult a physician.
SKIN: For skin contact, wash promptly with soap and excess water.
EYES: For eye contact, flush promptly with excess water for at least fifteen minutes. Consult a physician.
INGESTION: If ingested, do not induce vomiting. Give victim a glass of water. Call a physician
immediately.
PAGE 3 of 4 EPOXY STEEL HARDENER
=================================================================================
SECTION V I - REACTIVITY DATA
=================================================================================
STABILITY: Stable
CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge.
INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalis, oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide and Carbon.
HAZARDOUS POLYMERIZATION: Will not occur.
================================================================================
SECTION VII - SPILL AND DISPOSAL PROCEDURE
=================================================================================
SPILLS, LEAK OR RELEASE: Ventilate area. Remove all possible sources of ignition. Avoid prolonged
breathing of vapor. Contain spill with inert absorbent.
WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations.
================================================================================
SECTION VIII - PROTECTION INFORMATION
=================================================================================
RESPIRATORY PROTECTION: If component TLV limits are exceeded, use NIOSH/MSHA approved
respirator to remove vapors. Use an air-supplied respirator if necessary.
VENTILATION: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended levels.
Explosion-proof ventilation may be necessary.
PROTECTIVE GLOVES: To prevent prolonged exposure use rubber gloves; solvents may be absorbed through
the skin
EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields.
OTHER PROTECTIVE EQUIPMENT: Wear protective clothing as required to prevent skin contact.
=================================================================================
SECTION IX - HANDLING AND STORAGE PRECAUTIONS
=================================================================================
STORAGE AND HANDLING: Use with adequate ventilation. Avoid contact with eyes and skin. Avoid
breathing vapors. Do not store the product above 100F/38C. Do not flame, cut, braze weld or melt empty
containers. Keep the product away from heat, open flame, and other sources of ignition. Avoid contact with strong
acids, alkalis and oxidizers.
=================================================================================
SECTION X - ADDITIONAL INFORMATION
=================================================================================
SHIPPING INFORMATION: Please comply with DOT regulations in USA
HMIS RATING: Health 2 4 = Extreme
Fire 1 3 = High
Reactivity 1 2 = Moderate
1 = Slight
0 = Insignificant
Personal Protection - See Section VIII
=================================================================================
PAGE 4 of 4 EPOXY STEEL HARDENER
CALIFORNIA PROPOSITION 65:
Trace amounts of some chemicals known to the State of California to cause cancer, birth defects
or other reproductive harm may be present in this product.
SECTION 313 SUPPLIER NOTIFICATION:
This product contains the following toxic chemicals subject to the reporting requirements of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR 372:
CHEMICAL NAME CAS % BY WGT
NOT APPLICABLE
THIS INFORMATION MUST BE INCLUDED IN ALL MSDS THAT ARE COPIED AND DISTRIBUTED FOR THIS CHEMICAL
========================================================================================
ABBREVIATIONS
==================================================================
IARC = International Agency for Research on Cancer
ACGIH = American Conference of Governmental Industrial Hygienists
NIOSH = National Institute of Occupational Safety and Health
TLV = Threshold Limit Value
PEL = Permissible Emission Level
DOT = Department of Transportation
NTP = National Toxicology Program
N/AV = Not Available
N/AP = Not Applicable
N/E = Not Established
N/D = Not Determined
RESIN -
=================================================================================
SECTION II - HAZARDOUS INGREDIENTS
=====================================================================
INGREDIENTS WGT% CAS # TLV/PEL
Calcium Carbonate 40-50% 1317-65-3 ACGIH: TWA 10 mg/m3
OSHA: PEL 15 mppcf
Iron Powder 10-20% 65997-19-5 ACGIH TLV 15 mg/m3
OSHA: PEL 15 mppcf
Epoxy Resin 30-40% 25068-38-6 N/E
Aromatic Hydrocarbons 1-5 % 64742-94-5 N/E
=================================================================================
SECTION III - PHYSICAL DATA
=====================================================================
APPEARANCE: Dark gray or black smooth paste
SPECIFIC GRAVITY: 1.80
VAPOR PRESSURE (mmHG): N/Av
BOILING POINT: N/E
VAPOR DENSITY: Heavier than air
EVAPORATION RATE (Ethyl Ether = 1): Slower than Ethyl Ether
VOLATILES BY WEIGHT: N/D
SOLUBILITY IN WATER: Not Soluble
VOC: Grams/Liter = Nil
Lbs/Gallon = Nil
Page 2 Epoxy Steel Resin
==============================================================================
SECTION IV - FIRE AND EXPLOSION DATA
=================================================================================
FLASH POINT: >200F/ 93C Seta Flash Closed cup
LOWER FLAMMABLE LIMIT %: N/E
UPPER FLAMMABLE LIMIT %: N/E
FIRE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers with water
spray. Firefighter should wear OSHA/NIOSH approved self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARD: Closed containers exposed to high temperatures, such as fire
conditions may rupture.
=================================================================================
SECTION V - HEALTH HAZARD/TOXICOLOGICAL PROPERTIES
=================================================================================
OVEREXPOSURE EFFECTS:
ACUTE EFFECTS:
EYES: Contact with eyes can cause irritation, redness, tearing, blurred vision, and/or swelling.
SKIN: Contact with skin can cause irritation, (minor itching, burning and/or redness), Dermatitis,
defatting may be readily absorbed through the skin.
INHALATION: Inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness,
fatigue, nausea, headache, possible unconsciousness and/or asphyxiation. Aspiration of material into
lungs may result in chemical pneumonitis which can be fatal.
INGESTION: Ingestion can cause gastrointestinal irritation, nausea, vomiting, diarrhea.
CHRONIC EFFECTS:
Overexposure to this material has apparently been known to cause the following effects in lab animals:
skin sensitization, respiratory system irritation.
CARCINOGEN: YES _____ NO __X__
TERATOGEN: YES _____ NO __X__
MUTAGEN: YES _____ NO __X__
PRIMARY ROUTES OF EXPOSURE: skin, inhalation, eyes
FIRST AID:
INHALATION: If inhaled, remove victim from exposure to a well-ventilated area. Make them
comfortably warm, but not hot. Use oxygen or artificial respiration as required. Consult a physician.
SKIN: For skin contact, wash promptly with soap and excess water.
EYES: For eye contact, flush promptly with excess water for at least fifteen minutes. Consult a physician.
INGESTION: If ingested, do not induce vomiting. Give victim a glass of water. Call a physician
immediately.
Page 3 Epoxy Steel Resin
=================================================================================
SECTION V I - REACTIVITY DATA
=================================================================================
STABILITY: Stable
CONDITIONS TO AVOID: Open flames & heat. .
INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalis, oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide and Carbon.
HAZARDOUS POLYMERIZATION: Will not occur.
================================================================================
SECTION VII - SPILL AND DISPOSAL PROCEDURE
=================================================================================
SPILLS, LEAK OR RELEASE: Ventilate area. Remove all possible sources of ignition. Avoid prolonged
breathing of vapor. Contain spill with inert absorbent.
WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations.
================================================================================
SECTION VIII - PROTECTION INFORMATION
=================================================================================
RESPIRATORY PROTECTION: If component TLV limits are exceeded, use NIOSH/MSHA approved
respirator to remove vapors. Use an air-supplied respirator if necessary. With general ventilation, does not require a
respirator.
VENTILATION: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended levels.
PROTECTIVE GLOVES: To prevent prolonged exposure use rubber gloves; solvents may be absorbed through
the skin
EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields.
OTHER PROTECTIVE EQUIPMENT: Wear protective clothing as required to prevent skin contact.
=================================================================================
SECTION IX - HANDLING AND STORAGE PRECAUTIONS
=================================================================================
STORAGE AND HANDLING: Use with adequate ventilation. Avoid contact with eyes and skin. Avoid
breathing vapors. Do not store the product above 100F/38C. Do not flame, cut, braze weld or melt empty
containers. Keep the product away from heat, open flame, and other sources of ignition. Avoid contact with strong
acids, alkalis and oxidizers.
=================================================================================
SECTION X - ADDITIONAL INFORMATION
=================================================================================
SHIPPING INFORMATION: Please comply with DOT regulations in USA
HMIS RATING: Health 2 4 = Extreme
Fire 1 3 = High
Reactivity 1 2 = Moderate
1 = Slight
0 = Insignificant
Personal Protection - See Section VIII
=================================================================================
Page 4 Epoxy Steel Resin
CALIFORNIA PROPOSITION 65:
Trace amounts of epichlorohydrin, a chemical known to the State of California to cause cancer,
are present in this product. However, given the low level and application of this product, typical
uses do not constitute a significant risk under the standard.
SECTION 313 SUPPLIER NOTIFICATION:
This product contains the following toxic chemicals subject to the reporting requirements of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR 372:
CHEMICAL NAME CAS % BY WGT
Not Applicable
THIS INFORMATION MUST BE INCLUDED IN ALL MSDS THAT ARE COPIED AND DISTRIBUTED FOR THIS CHEMICAL
========================================================================================
ABBREVIATIONS
==================================================================
IARC = International Agency for Research on Cancer
ACGIH = American Conference of Governmental Industrial Hygienists
NIOSH = National Institute of Occupational Safety and Health
TLV = Threshold Limit Value
PEL = Permissible Emission Level
DOT = Department of Transportation
NTP = National Toxicology Program
N/AV = Not Available
N/AP = Not Applicable
N/E = Not Established
N/D = Not Determined