Sure but your average USB charger can not deliver that much power. Basic Chinese phone chargers are 2A at 5V written on the tin and most often their voltage collapses above 1A. Power Banks are often also pretty limited, and USB2 ports on computer are only 0.5A per spec (some go slightly higher tho but nowhere near the power you are after)
A real charger able to deliver 100W looks more like an hefty brick and I just looked on amazon, they also cost more than an equivalent standard PSU of comparable power. So if you already have one for your fancy phone, why not. Although charging cells that fast does lower their service life, so that's not something I would do personally (but hey Apple wants you to buy a new phone every couple of years so that is in their interest!)
Anyway the PSU is only part of the problem, you would need to be able to regulate those 100W somehow or you'll combust in no time, or worse make your heater go pop! Perhaps using the PD protocol you could change the PSU settings on the fly and select a few different delivery profiles, but that would fall short compared to a real temperature control.